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Popowski, Yanay ; Moreno, Juan J. ; Nichols, Asa W. ; Hooe, Shelby L. ; Bouchey, Caitlin J. ; Rath, Nigam P. ; Machan, Charles W. ; Tolman, William B. ( , Chemical Communications)null (Ed.)Pentacoordinate Al catalysts comprising bipyridine (bpy) and phenanthroline (phen) backbones were synthesized and their catalytic activity in epoxide/anhydride copolymerization was investigated and compared to ( t-Bu salph)AlCl. Stoichiometric reactions of tricyclic anhydrides with Al alkoxide complexes produced ring-opened products that were characterized by NMR spectroscopy, mass spectrometry, and X-ray crystallography, revealing key regio- and stereochemical aspects.more » « less
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Luke, Anna M. ; Peterson, Appie ; Chiniforoush, Sina ; Mandal, Mukunda ; Popowski, Yanay ; Sajjad, Hussnain ; Bouchey, Caitlin J. ; Shopov, Dimitar Y. ; Graziano, Brendan J. ; Yao, Letitia J. ; et al ( , Macromolecules)
